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研究室简介 查看详情+
本研究室重点从事面向化工、能源、环境等领域应用的MOF和COF两类新型多孔材料及其复合材料的吸附分离、膜分离性能研究,采用的研究手段包括计算(量化计算、分子模拟、材料基因组学等)和实验两种技术,形成了“计算引领下的新材料研发”研究模式。
研究室现有固定研究成员12人,其中长江学者/国家杰出青年基金获得者1人,优青1人,正高级职称1人,副高级职称6人,中级职称3人。
研究室主任 查看详情+

仲崇立教授,博导

仲崇立,教授,博士生导师,天津工业大学省部共建分离膜与膜过程国家重点实验室主任、化学工程与技术学院院长。1993年获北京化工大学工学博士学位,先后在日本广岛大学和荷兰Delft University of Technology任助理教授、博士后研究员,1999年9月至2018年12月任北京化工大学化工学院教授,2019年1月至今,任职于天津工业大学。曾任国家自然科学基金项目会评专家、科技部“973计划”项目复评专家。 长期从事面向化工、环境与能源等领域应用的纳微结构材料的分子设计、合成与性能研究,特别是MOF/COF及其复合材料的吸附分离与膜分离性能研究。主持并完成国家杰出青年基金、国家自然科学基金重点项目和国家“973”计划课题等各类项目多项。发表论文300余篇,其中包括化工四大期刊50余篇和影响因子10以上40余篇(Chem. Rev., Nat. Mater., Nat. Catalysis, Adv. Mater., JACS等),被Nature及Science等期刊他引1万余次,单篇引用次数超过100次的论文25篇;出版中文专著2部;获授权发明专利13件,软件著作权2件;获得2021年天津市自然科学一等奖,其他科技和人才奖励8项;主持科技部重点研发计划(2021);入选全国杰出专业技术人才(2021)、长江学者特聘教授(2013年)、国家杰青(2007年)、国务院“享受政府特殊津贴专家”(2002年)等。
发表论文与专著 查看更多+
  • 1、

    J. Li, M. Du, Z. Wu, X. Zhang, W. Xue, H. Huang, C. Zhong, Engineering single-atom sites with the Irving-Williams series for the simultaneous co-photocatalytic CO2 reduction and CH3CHO oxidation, Angew. Chem. Int. Ed., 2024, 63, e202407975.

  • 2、

    Y, Liang, Z. Zhang, A. Chen, C. Yu, Y. Sun, J. Du, Z. Qiao, Z. Wang, M. D. Guiver, C. Zhong, Large-area ultrathin metal-organic framework membranes fabricated on flexible polymer supports for gas separations, Angew. Chem. Int. Ed., 2024, 63, e202404058.

  • 3、

    D. Ao, Z. Yang, A. Chen, Y. Sun, M. Ye, L. Tian, X. Cen, Z. Xie, J. Du, Z. Qiao, A. K. Cheetham, J. Hou, C. Zhong, Effective C4 separation by zeolite metal-organic framework composite membranes,  Angew. Chem. Int. Ed., 2024, 63, e202401118.

  • 4、

    M. Zheng, W. Xue, T. Yan, Z. Jiang, Z. Fang, H. Huang, C. Zhong, Fluorinated MOF-based hexafluoropropylene nanotrap for highly efficient purification of octafluoropropane electronic specialty gas, Angew. Chem. Int. Ed., 2024, 63, e202401770.

  • 1、

    Z. Yang, Y. Belmabkhout, L. N. McHugh, D. Ao, Y. Sun, S. Li, Z. Qiao, T. D. Bennett, M. D. Guiver, C. Zhong, ZIF-62 glass foam self-supported membranes to address CH4/N2 separations, Nat. Mater., 2023, 22, 888-894.

  • 2、

    C. Yu, X. Cen, Z. Zhang, Y. Sun, W. Xue , Z. Qiao, M. D. Guiver, C. Zhong, Step-nucleation in situ self-repair to prepare rollable large-area ultrathin MOF membranes, Adv. Mater., 2023, 35, 2307013.

  • 3、

    D. Ao, Z. Yang, Z. Qiao, Y. Sun, Z. Zhang, M. D. Guiver, C. Zhong, Metal–organic framework crystal–glass composite membranes with preferential permeation of ethane, Angew. Chem. Int. Ed., 2023, 62, e202304535.

  • 4、

    L. Wang, W. Xue, H. Zhu, X. Guo, H. Huang, C. Zhong, Stepwise engineering of a cage-like MOF pore aperture for the efficient separation of isomeric C4 paraffins under humid conditions, Angew. Chem. Int. Ed., 2023, 62, e202218596.

  • 1、

    Y. Chang, H. Huang, H. Zhu, Y. Zhao, L. Wang, Y. Sun, C. Zhong, Robust carbazole-based covalent triazine frameworks with defective ultramicropore structure for efficient ethane-selective ethane-ethylene separation, Chem. Eng. J., 2022, 427, 131726.

  • 2、

    X. Liang, H. Wu, H. Huang, X. Wang, M. Wang, H. Dou, G. He, Y. Ren, Y. Liu, Y. Wu, S. Wang, H. Ge, C. Zhong, Y. Chen, Z. Jiang, Efficient ethylene/ethane separation through ionic liquid-confined covalent organic framework membranes, J. Mater. Chem. A, 2022, 10, 5420-5429.

  • 3、

    Z. Zhang, X. Cao, C. Geng, Y. Sun, Y. He, Z. Qiao, C. Zhong, Machine Learning Aided High-throughput Prediction of Ionic Liquid@MOF Composites for Membrane-based CO2 Capture, J. Membr. Sci., 2022, 650, 120399.

  • 4、

    Y. Sun, L. Tian, Z. Qiao, C. Geng, X. Guo, C. Zhong, Surface modification of bilayer structure on metal-organic frameworks towards mixed matrix membranes for efficient propylene/propane separation, J. Membr. Sci., 2022, 648, 120350.

  • 1、

    J. Li, H. Huang, W. Xue, K. Sun, X. Song, C. Wu, L. Nie, Y. Li, C. Liu, Y. Pan, H.-L. Jiang, D. Mei, C. Zhong, Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4. Nat. Catal., 2021, 4, 719–729.

  • 2、

    Y. Ying, Z. Zhang, S. B. Peh, A. Karmakar, Y. Cheng, J. Zhang, L. Xi, C. Boothroyd, Y. M. Lam, C. Zhong, D. Zhao, Pressure-responsive two-dimensional metal-organic framework composite membranes for CO2 separation, Angew. Chem. Int. Ed., 2021, 60, 11318-11325.

  • 3、

    G. Han, N. Yu, D. Liu, G. Yu, X. Chen, C. Zhong, Stepped enhancement of CO2 adsorption and separation in IL-ZIF-IL composites with shell-interlayer-core structure, AIChE J., 2021, 67, 17112.

  • 4、

    X. Guo, S. Xu, Y. Sun, Z. Qiao, H. Huang, C. Zhong, Metal-organic polyhedron membranes for molecular separation, J. Membr. Sci., 2021, 632, 119354.

  • 1、

    Z. Qiao, Y. Liang, Z. Zhang, Z. Wang, M. D. Guiver, C. Zhong, Ultrathin low-crystallinity MOF membranes fabricated by interface layer polarization induction, Adv. Mater., 2020, 32, 2002165.

  • 2、

    J. Li, P. Liu, Y. Tang, H. Huang, H. Cui, D. Mei, C. Zhong, Single-Atom Pt-N3 Sites on the Stable Covalent Triazine Framework Nanosheets for Photocatalytic N2 Fixation, ACS Catal., 2020, 10, 2431-2442.

  • 3、

    Y. Liang, C. Yu, J. Ju, Z. Qiao, C. Zhong, Polymer-supported ultra-thin two-dimensional ZIF-L membranes through in-situ interface exfoliation for gas separation, Sci. Bull., 2020, 65, 1788-1791.

  • 4、

    X. Liu, F. Tian, T. Yue, X. Zhang, C. Zhong, Radial aggregation of proteins prevails over axial aggregation on membrane tubes, Nanoscale, 2020, 12, 3029-3037.

  • 1、

    Z. Qiao, S. Zhao, M. Sheng, J. Wang, S. Wang, Z. Wang, C. Zhong, M. D. Guiver, Metal-induced ordered microporous polymers for fabricating large-area gas separation membranes, Nat. Mater., 2019, 18, 163-168.

  • 2、

    Q. Tan, H. Huang, Y. Peng, Y. Chang, Z. Zhang, D. Liu, C. Zhong, A temperature-responsive smart molecular gate in a metal-organic framework for task-specific gas separation, J. Mater. Chem. A, 2019, 7, 26574-26579.

  • 3、

    X. Guo, Z. Qiao, D. Liu, C. Zhong, Mixed-matrix membranes for CO2 separation: role of the third component, J. Mater. Chem. A, 2019, 7, 24738-24759.

  • 4、

    J. Li, H. Huang, Y. Li, Y. Tang, D. Mei, C. Zhong, Stable and size-controllable ultrafine Pt nanoparticles derived from a MOF-based single metal ion trap for efficient electrocatalytic hydrogen evolution, J. Mater. Chem. A, 2019, 7, 20239-20246.

  • 1、

    Y. Lan, X. Han, M. Tong, H. Huang, Q. Yang, D. Liu, X. Zhao, C. Zhong, Materials genomics methods for high-throughput construction of COFs and targeted synthesis, Nat. Commun., 2018, 9, 5274.

  • 2、

    Y. Peng, H. Huang, Y. Zhang, C. Kang, S. Chen, L. Song, D. Liu, C. Zhong. A versatile MOF-based trap for heavy metal ion capture and dispersion. Nat. Commun., 2018, 9, 187.

  • 3、

    W. Zhang, D. Liu, X. Guo, H. Huang, C. Zhong, Fabrication of mixed-matrix membrane with MOF-derived porous carbon for CO2 separation. AIChE J., 2018, 64, 3400-3409.

  • 4、

    C. Zhang, Y. Lan, X. Guo, Q. Yang, C. Zhong, Materials Genomics-Guided Ab Initio Screening of MOFs with Open Copper Sites for Acetylene Storage. AIChE J., 2018, 64, 1389-1398.

  • 1、

    X. Guo, D. Liu, T. Han, H. Huang, Q. Yang, C. Zhong. Preparation of Thin Film Nanocomposite Membranes with Surface Modified MOF for High Flux Organic Solvent Nanofiltration. AIChE J., 2017, 63,1303-1312.

  • 2、

    W. Zhang, Y. Ying, J. Ma, X. Guo, H. Huang, D. Liu and C. Zhong, Mixed matrix membranes incorporated with polydopamine-coated metal-organic framework for dehydration of ethylene glycol by pervaporation, J. Membr. Sci., 2017, 527, 8-17.

  • 3、

    M. Tong, Y. Lan, Q. Yang, C. Zhong, Exploring the structure-property relationships of covalent organic frameworks for noble gas separations, Chem. Eng. Sci., 2017, 168, 456-464.

  • 4、

    J. Ma, X. Guo, Y. Ying, D. Liu, C. Zhong, Composite ultrafiltration membrane tailored by MOF@GO with highly improved water purification performance, Chem. Eng. J., 2017, 313, 890-898.

  • 1、

    S. Li, K. Wang, Y. Shi, Y. Cui, B. Chen, B. He, W. Dai, H. Zhang, X. Wang, C. Zhong, H. Wu, Q. Yang, Q. Zhang, Novel Biological Functions of ZIF-NP as a Delivery Vehicle: High Pulmonary Accumulation, Favorable Biocompatibility, and Improved Therapeutic Outcome. Adv. Funct. Mater., 2016, 26, 2715-2727.

  • 2、

    W. Tang, J. Gu, H. Huang, D. Liu, C. Zhong. Metal-Organic Frameworks for Highly Efficient Adsorption of Dibenzothiophene from Liquid Fuels. AIChE J., 2016, 62, 4491-4496.

  • 3、

    Y. Ying, D. Liu, J. Ma, M. Tong, W. Zhang, H. Huang, Q. Yang, C. Zhong. A GO-assisted method for the preparation of ultrathin covalent organic framework membranes for gas separation, J. Mater. Chem. A, 2016, 4, 13444-13449.

  • 4、

    J. Ma, Y. Ying, X. Guo, H. Huang, D. Liu, C. Zhong, Fabrication of mixed-matrix membrane containing metal-organic framework composite with task specific ionic liquid for efficient CO2 separation, J. Mater. Chem. A, 2016, 4, 7281-7288.

  • 1、

    H. Huang, J. Li, K. Wang, T. Han, M. Tong, L. Li, Y. Xie, Q. Yang, D. Liu, C. Zhong, In-Situ Self-Assembly Template Strategy for the Preparation of Hierarchical-Pore Metal-Organic Frameworks, Nat. Commun., 2015, 6, 8847.

  • 2、

    D. Liu, T.-F. Liu, Y.-P. Chen, L. Zou, D. Feng, K. Wang, Q. Zhang, S. Yuan, C. Zhong, H.-C. Zhou, A Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications, J. Am. Chem. Soc., 2015, 137, 7740-7746.

  • 3、

    Y. Ban, Z. Li, Y. Li, Y. Peng, H. Jin, W. Jiao, A. Guo, P. Wang, Q. Yang, C. Zhong, W. Yang, Confinement of ionic liquid into nanocage: tailoring molecular sieving property of ZIF-8 for membrane-based CO2 capture, Angew. Chem. Int. Ed., 2015, 54, 15483-15487.

  • 4、

    T. Han, Y. Xiao, M. Tong, H. Huang, D. Liu, L. Wang, C. Zhong, Synthesis of CNT@MIL-68(Al) composites with improved adsorption capacity for phenol in aqueous solution, Chem. Eng. J., 2015, 275, 134-141.

  • 1、

    Z. Li, G. Xiao, Q. Yang, Y. Xiao, C. Zhong. Computational exploration of metal-organic Frameworks for CO2/CH4 separation via temperature swing adsorption, Chem. Eng. Sci., 2014, 120, 59-66.

  • 2、

    L. Xie, D. Liu, H. Huang, Q. Yang, C. Zhong, Efficient capture of nitrobenzene from waste water using metal-organic frameworks, Chem. Eng. J., 2014, 246, 142-149.

  • 3、

    D. Wu, G. Maurin, Q. Yang, C. Serre, H. Jobic, C. Zhong, Computational exploration of a Zr-carboxylate based metal-organic framework as a membrane material for CO2 capture, J. Mater. Chem. A, 2014, 2, 1657-1661.

  • 4、

    Q. Ma, Q. Yang, A. Ghoufi, M. Lei, G. Ferey, C. Zhong, G. Maurin, Guest-modulation of the mechanical properties of flexible porous Metal Organic Frameworks, J. Mater. Chem. A, 2014, 2, 9691-9698.

  • 1、

    Q. Yang, D. Liu, C. Zhong, J. Li, Development of Computational Methodologies for Metal-Organic Frameworks and Their Application in Gas Separations, Chem. Rev., 2013, 113, 8261-8323.

  • 2、

    Q. Yang, S. Vaesen, F. Ragon, A.D. Wiersum, D. Wu, A. Lago, T. Devic, C. Martineau, F. Taulelle, P.L. Llewellyn, H. Jobic, C. Zhong, C. Serre, G. De Weireld, G. Maurin, A Water Stable Metal-Organic Framework with Optimal Features for CO2 Capture, Angew. Chem. Int. Ed., 2013, 52, 10316-10320.

  • 3、

    D. Zhou, F. Zhang, J. Mi, C. Zhong, Line Tension and Contact Angle of Heterogeneous Nucleation of Binary Fluids, AIChE J., 2013, 59, 4390-4398.

  • 4、

    M. Tong, D. Liu, Q. Yang, S. Devautour-Vinot, G. Maurin, C. Zhong, Influence of the framework metal ions on the dye capture behavior of the MIL-100(Fe, Cr) MOF type solids, J. Mater. Chem. A, 2013, 1, 8534-8537.

  • 1、

    D. Wu, C. Wang, B. Liu, D. Liu, Q. Yang, C. Zhong, Large-scale computational screening of metal-organic frameworks for CH4/H2 separation, AIChE J., 2012, 58, 2078-2084.

  • 2、

    F. Cao, C. Zhang, Y. Xiao, H. Huang, W. Zhang, D. Liu, C. Zhong, Q. Yang, Z. Yang, X. Lu, Helium recovery by a cubtc metal-organic framework membrane, Ind. Eng. Chem. Res., 2012, 51, 11274-11278.

  • 3、

    H. Zhang, H. Huang, C, Li. H, Meng. Y, Lu. C. Zhong, D. Liu, Q. Yang, Adsorption behavior of metal-organic framework for thiophenic sulfur from diesel oil, Ind. Eng. Chem. Res., 2012, 51, 12449-12455.

  • 4、

    H. Huang, W. Zhang, D. Liu, C. Zhong, Understanding the effect of trace amount of water on CO2 capture in natural gas upgrading in metal-organic frameworks: a molecular simulation study, Ind. Eng. Chem. Res., 2012, 51, 10031-10038.

  • 1、

    H. Huang, W. Zhang, D. Liu, B.Liu, G. Chen, C. Zhong, Effect of temperature on gas adsorption and separation in ZIF-8: a combined experimental and molecular simulation study, Chem. Eng. Sci., 2011, 66, 6297-6305.

  • 2、

    Q. Yang, L. Ma, C. Zhong, X. An, D. Liu, Enhancement of CO2/N2 mixture separation using the thermodynamic stepped behavior of adsorption in metal−organic frameworks, J. Phys. Chem. C, 2011, 115, 2790-2797.

  • 3、

    W. Mu, D. Liu, C. Zhong, A computational study of the effect of doping metals on CO2/CH4 separation in metal-organic frameworks, Microporous Mesoporous Mater., 2011, 143, 66-72.

  • 4、

    L. Zhao, Q. Yang, Q. Ma, C. Zhong, J. Mi, D. Liu, A force field for dynamic Cu-BTC metal-organic framework, J. Mol. Model., 2011, 17, 227-234.

  • 1、

    D. Liu, C. Zhong, Characterization of Lewis acid sites in metal-organic frameworks using density functional theory, J. Phys. Chem. Lett., 2010, 1, 97-101.

  • 2、

    Y. Liu, D. Liu, Q. Yang, C. Zhong, J. Mi, Comparative study of separation performance of COFs and MOFs for CH4/CO2/H2 mixtures, Ind. Eng. Chem. Res., 2010, 49, 2902-2906.

  • 3、

    D. Liu, C. Zhong, Understanding gas separation in metal-organic frameworks using computer modeling, J. Mater. Chem., 2010, 20, 10308-10318.

  • 4、

    Q. Xu, D. Liu, Q. Yang, C. Zhong, J. Mi, Li-modified metal-organic frameworks for CO2/CH4 separation: a route to achieving high adsorption selectivity, J. Mater. Chem., 2010, 20, 706-714.

  • 1、

    仲崇立编著,绿色化学导论,化学工业出版社,2000年

  • 2、

    仲崇立、刘大欢、阳庆元著,金属-有机骨架材料的构效关系及设计,科学出版,2013年

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